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Ask experts Expert Question: although LiCl has higher lattice energy than NaCl but still LiCl HAS LOWER MELTNG PT NaCl
Reply Forum Index -> Inorganic Chemistry originally posted here on IIT-JEE / AIEEE community   
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ANISH RAO (5)

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Olaaa!! Perrrfect answer. 1  [1 rates]

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although LiCl has higher lattice energy than NaCl but still LiCl HAS LOWER MELTNG PT NaCl
    

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Pranjal Tomar (40)

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 http://wiki.answers.com/Q/Why_melting_point_of_LiCl_is_lower_than_NaCl

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ANISH RAO (5)

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dont know but i m still not completely convinced...//but there is a point in dis ans,
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Krishna Gopal Singh (4613)

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Right answer by Pranjal. Here I would like to add one more point. As size of Li+ ion is very small as compared to Na+ ion it does not fits as well as Na+ in the Cl- latice. This also gives it lower melting point.
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