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Catalogs Discussion Forums -> Organic Chemistry -> Write the equations of the reactions which take place when 1- propanol is treated with (iii) acidif -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

CH3CH2CH2OH + KMnO4/H+ ------------------------>CH3CH2COOH  i.e. propanoic acid.

Catalogs Discussion Forums -> Mechanics -> A large tank filled with water to a height 'h'is to be emptied through a small hole at the bottom.Wh -> Go to message
This Post 2 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]

let A be area of vessel.

a be area of hole

at any time let H be level of water in the vessel.

Time taken for water level to get reduced from H to 0 is given by  

Time taken for water level to get reduced from H/2 to 0 is given by

therefore Time taken for water level to get reduced from H to H/2 is given by (T1)=

  ---      ---------------------1

and Time taken for water level to get reduced from H/2 to 0 is given by (T2) =    -------------2

 

on dividing eqn 1 by 2 we get. T1/T2 =

Catalogs Discussion Forums -> Physical Chemistry -> can anybody tell me why the dipolar moment of nitrecyclehexane (C6H11NO2) is larger than the dipolar -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

the dipolar moment of nitrocyclohexane  is larger than the dipolar moment of nitobenzene because in nitrocyclohexane dipole moment due to lone pair is outwards completely and in nitobenzene the lone pair is in conjugation with the multiple bond of the benzene ring, therefore dipole moment due to the lone pair gats reduced to a large extent.

Catalogs Discussion Forums -> Organic Chemistry -> wt hybridezen in ph3 ,h2s -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

For PH3 Hybridization is not defined- refer to drago's rule for more explaination.

H2S- its hybridization is SP3

Catalogs Discussion Forums -> Organic Chemistry -> how we can convert aldehyde into acetic acid -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

either you should mention a particular aldehyde or the question should be conversion of aldehydes into carboxylic acid and in that case answer would be as followed:-

Aldehyde can be converted into carboxylic acid by its oxidation with a strong oxidising agents like KMnO4/H+ or K2Cr2O7/H+ ,i.e. in presence of strong acid.

Catalogs Discussion Forums -> Organic Chemistry -> Write the equations of the reactions which take place when 1- propanol is treated with SOCl2. -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

When 1- propanol is treated with SOCl2, following reaction takes place

CH3-CH3-CHOH + SOCl2 -----> CH3CH2CHCl+SO2+HCl

Catalogs Discussion Forums -> Organic Chemistry -> what is enendthermic and exothermic reaction -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

Many chemical reactions release energy in the form of heat, light, or sound. These are exothermic reactions. Exothermic reactions may occur spontaneously and result in higher randomness or entropy (ΔS > 0) of the system. They are denoted by a negative heat flow (heat is lost to the surroundings) and decrease in enthalpy (ΔH < 0). In the lab, exothermic reactions produce heat or may even be explosive.

There are other chemical reactions that must absorb energy in order to proceed. These are endothermic reactions. Endothermic reactions cannot occur spontaneously. Work must be done in order to get these reactions to occur. When endothermic reactions absorb energy, a temperature drop is measured during the reaction. Endothermic reactions are characterized by positive heat flow (into the reaction) and an increase in enthalpy (+ΔH).

Examples of Endothermic and Exothermic Processes

Photosynthesis is an example of an endothermic chemical reaction. In this process, plants use the energy from the sun to convert carbon dioxide and water into glucose and oxygen. This reaction requires 15MJ of energy (sunlight) for every kilogram of glucose that is produced:

sunlight + 6CO2(g) + H2O(l) = C6H12O6(aq) + 6O2(g)

An example of an exothermic reaction is the mixture of sodium and chlorine to yield table salt. This reaction produces 411 kJ of energy for each mole of salt that is produced:

Na(s) + 0.5Cl2(s) = NaCl(s)

 

Catalogs Discussion Forums -> Organic Chemistry -> what is endothermic and exothermic -> Go to message
This Post 2 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]

Many chemical reactions release energy in the form of heat, light, or sound. These are exothermic reactions. Exothermic reactions may occur spontaneously and result in higher randomness or entropy (ΔS > 0) of the system. They are denoted by a negative heat flow (heat is lost to the surroundings) and decrease in enthalpy (ΔH < 0). In the lab, exothermic reactions produce heat or may even be explosive.

There are other chemical reactions that must absorb energy in order to proceed. These are endothermic reactions. Endothermic reactions cannot occur spontaneously. Work must be done in order to get these reactions to occur. When endothermic reactions absorb energy, a temperature drop is measured during the reaction. Endothermic reactions are characterized by positive heat flow (into the reaction) and an increase in enthalpy (+ΔH).

Examples of Endothermic and Exothermic Processes

Photosynthesis is an example of an endothermic chemical reaction. In this process, plants use the energy from the sun to convert carbon dioxide and water into glucose and oxygen. This reaction requires 15MJ of energy (sunlight) for every kilogram of glucose that is produced:

sunlight + 6CO2(g) + H2O(l) = C6H12O6(aq) + 6O2(g)

An example of an exothermic reaction is the mixture of sodium and chlorine to yield table salt. This reaction produces 411 kJ of energy for each mole of salt that is produced:

Na(s) + 0.5Cl2(s) = NaCl(s)

 

Catalogs Discussion Forums -> Mechanics -> The pendulum of a clock is replaced by a spring mass system with the spring having spring constant 0 -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

we know that time period of the pendulum = 1s.

also time period of spring mass system =

therefore by equating time period by 1 we get

m = 4π2k

here k = 0.1

therefore m =3.947 kg.

Catalogs Discussion Forums -> Mechanics -> the velocity of a particle ia 6i+2j-2k. the component of the velocity of a particle to vector i+j+k -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

vector V =6i+2j-2k

let any other vector U = i+j+k

component of V along U is given by [(V. u-hat)] u-hat

we know that modulus of U here is

V.U = (6*1)+(2*1)-(2*1)

   = 6

also

u-hat equals the vector u divided by its length



therefore required answer is = 

            =2i+2j+2k






 

Catalogs Discussion Forums -> General Physics -> what is plasma state ? -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

The plasma state is the fourth  state of matter and the most diffused in the  Universe. It is characterized by the absence of  molecular bond for biatomic gases such as  Nitrogen and Hydrogen and atomic bond for  mono atomic gases such as Argon and Helium. By  supplying  HEAT ENERGY to a biatomic gas,  its molecule breaks into atoms and atoms by further energy, break  into one or more positive charges.
Hence the plasma state is an ionized gas, formed  by positive ions and negative electrons of the  gas initially in neutral condition and is a very  good conductor of electricity and is affected by  magnetic fields.

.

Plasma is so energetic or "hot" that in space it consists soley of ions and electrons. It is only when plasma is cooled that the atoms or molecules that are so predominant in forming gases, liquids, and solids that we are so accustomed to on Earth, is possible. So, in space, plasma remains electrically charged. Thus plasmas carry electric currents and are more influenced by electromagnetic forces than by gravitational forces. Outside the Earth's atmosphere, the dominant form of matter is plasma, and "empty" space has been found to be quite "alive" with a constant flow of plasma.

Catalogs Discussion Forums -> Trignometry -> sin 72 - sin 60 =? -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]

we know that sin(90-A) =cos A

therefore sin 72 = cos 18

we know that cos 18=

and sin60 =

therefore rquired value =    - 

solve it and get the answer

Catalogs Discussion Forums -> Organic Chemistry -> How can we get C6H3(Ch3)3 from acetylene -> Go to message
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Catalogs Discussion Forums -> Organic Chemistry -> HOW IS ADIPIC ACID FORMED?? -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
KMnO4 oxidation -2
Catalogs Discussion Forums -> Organic Chemistry -> mechanism of preperation acetanilide from anilin -> Go to message
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Catalogs Discussion Forums -> Organic Chemistry -> what is the structure of so3? -> Go to message
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Catalogs Discussion Forums -> Organic Chemistry -> how can isomerization be brought about in alkynes by use of soda amide in presence of ammonia? -> Go to message
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Catalogs Discussion Forums -> Organic Chemistry -> distinguish between oppenear and MPV rxn with eg..... -> Go to message
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Catalogs Discussion Forums -> Organic Chemistry -> conversion of benzamide to toluene -> Go to message
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Catalogs Discussion Forums -> Organic Chemistry -> structures of isomeric butyl benzene -> Go to message
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